Salinity in the South Platte Basin

Presented at the 2008 Central Plains irrigation conference on February 19-20 in Greeley, Colorado.An abstract of the paper presented

SCADA and related technologies

Presented at SCADA and related technologies for irrigation district modernization, II: a USCID water management conference held on June 6-9, 2007 in Denver, Colorado.Northern Water (Northern Colorado Water Conservancy District) conducted field demonstrations and comparisons of flow monitoring equipment at 18 canal and ditch sites in the lower South Platter River Basin during the 2006 irrigation season. Equipment included data loggers from 8 different manufacturers, 16 different models of water level sensors from 12 manufacturers, and 4 different types of telemetry from 7 manufacturers. The data loggers that were demonstrated included four models of single-sensor with integrated data logger, four models of programmable multi-sensor data logger, and one model of basic, low-cost data logger without telemetry. Relative equipment costs for each data logger system are summarized in Table 6. The water level sensors tested included submersible pressure transducers, optical shaft encoders, ultrasonic distance sensors, bubbler level sensor, float and pulley with potentiometer, buoyancy sensor, and a laser distance sensor. Bench checks of sensor calibrations were accomplished by Northern Water staff before field installation, and again at the end of the irrigation season. Observed sensor accuracy was compared to that expected from manufacturer specifications. The telemetry systems tested in the field included license-free spread-spectrum radios from four manufacturers, licensed radio modems in the 450 MHz range, satellite radio modems to a web server, and cdma modems with static IP addresses. Increased mast height and high gain directional antenna improved radio telemetry as expected. Additionally, operational files were utilized to document telemetry performance when available. The purpose and intent of the equipment demonstration and comparison was not to identify a single best data logger, sensor, and/or telemetry system. Each has different features and strengths, as well as varying costs. For each specific flow monitoring application, different equipment may be preferred or better suited than other equipment. However, the 2006 demonstration and comparison should provide a reference point for those seeking to become more knowledgeable in equipment selection while avoiding unpleasant surprises

Three red suns in the sky: A transiting, terrestrial planet in a triple M-dwarf system at 6.9 pc

We present the discovery from Transiting Exoplanet Survey Satellite (TESS) data of LTT 1445Ab. At a distance of 6.9 pc, it is the second nearest transiting exoplanet system found to date, and the closest one known for which the primary is an M dwarf. The host stellar system consists of three mid-to-late M dwarfs in a hierarchical configuration, which are blended in one TESS pixel. We use MEarth data and results from the Science Processing Operations Center data validation report to determine that the planet transits the primary star in the system. The planet has a radius of ${1.38}_{-0.12}^{+0.13}$ ${R}_{\oplus }$, an orbital period of ${5.35882}_{-0.00031}^{+0.00030}$ days, and an equilibrium temperature of ${433}_{-27}^{+28}$ K. With radial velocities from the High Accuracy Radial Velocity Planet Searcher, we place a 3σ upper mass limit of 8.4 ${M}_{\oplus }$ on the planet. LTT 1445Ab provides one of the best opportunities to date for the spectroscopic study of the atmosphere of a terrestrial world. We also present a detailed characterization of the host stellar system. We use high-resolution spectroscopy and imaging to rule out the presence of any other close stellar or brown dwarf companions. Nineteen years of photometric monitoring of A and BC indicate a moderate amount of variability, in agreement with that observed in the TESS light-curve data. We derive a preliminary astrometric orbit for the BC pair that reveals an edge-on and eccentric configuration. The presence of a transiting planet in this system hints that the entire system may be co-planar, implying that the system may have formed from the early fragmentation of an individual protostellar core.Accepted manuscrip

Crystallisation and fractionation of selected polyhydroxyalkanoates produced from mixed cultures

Poly[R-3-hydroxybutyrate-co-(R-3-hydroxyvalerate)] (PHBV) copolymers were produced from mixed cultures of biomass (activated sludge) fed with acetic acid (HAc) and propionic acid (HPr). Feeding was performed in such a way as to produce materials with a wide range of monomer compositions and microstructures. Solvent-cast thin films of these materials have recently been shown to exhibit a narrow range of mechanical properties similar to those of the homopolymer poly(R-3-hydroxybutyrate) (PHB) [1]. In this work, more detailed analyses of the thermal and crystallisation properties of these mixed-culture polyesters have revealed that they like comprise complex blends with broad compositional distribution of random and/or blocky copolymers of very different 3-hydroxyvalerate (3HV) contents and melting temperatures and thus have very different respective crystallisation kinetics. This blend complexity was confirmed by solvent fractionation of selected samples. The findings support the hypothesis that overall mechanical properties of these complex copolymer blend materials will be strongly influenced by the more rapidly crystallising components that form the matrix within which the slower crystallising components exist as microdomains. New opportunities in the material development of PHAs are likely to be found in establishing and exploiting such structure-function relationships

In-line monitoring of thermal degradation of PHA during melt-processing by Near-Infrared spectroscopy

Polyhydroxyalkanoate (PHA) biopolymer processing is often challenged by low thermal stability, meaning that the temperatures and time for which these polymers can be processed is restrictive. Considering the sensitivity of PHA to processing conditions, there is a demand for in-line monitoring of the material behaviour in the melt. This paper investigates the application of Near-Infrared (NIR) spectroscopy for monitoring the thermal degradation of PHAs during melt-processing. Two types of materials were tested: two mixed culture PHAs extracted from biomass produced in laboratory and pilot scale after an acidic pre-treatment, and two commercially available materials derived from pure culture production systems. Thermal degradation studies were carried out in a laboratory scale extruder with conical twin screws connected to a NIR spectrometer by a fibre optic to allow in situ monitoring. Multivariate data analysis methods were applied for assessing thermal degradation kinetics and predicted the degree of degradation as measured by H-1 NMR (proton nuclear magnetic resonance spectroscopy). The pre-treated mixed culture PHAs were found to be more thermally stable when compared with the commercial pure culture PHAs as demonstrated by NIR, H-1 NMR and GPC (gel permeation chromatography)

Thermal properties and crystallization behavior of fractionated blocky and random polyhydroxyalkanoate copolymers from mixed microbial cultures

This study represents the first detailed analysis of the thermal, morphological, and crystallization properties of the blend components within a range of mixed-culture polyhydroxyalkanoates (PHAs), with 3-hydroxyvalerate content in the as-produced materials and in the fractions ranging from low (12 mol %) to high (91 mol %). Both coarse and fine fractionation of the as-produced copolymers confirmed that they were blends of nominally blocky and/or random copolymers of poly(3-hydroxybutyrate-co-3-hydroxyvalerate), with very broad compositional distributions as governed by the PHA accumulation strategy. The crystallization kinetics and thermal properties of the fractions were found to be very significantly different from each other, consistent with the hypothesis that the overall mechanical properties were primarily controlled by the more rapidly crystallizing components. Two materials produced using an alternating feeding strategy demonstrated unique crystallization and thermal properties in their fractions, which are considered to have contributed to distinctly more elastic mechanical properties in these particular samples

Physicochemical and mechanical properties of mixed culture polyhydroxyalkanoate (PHBV)

The mechanical properties of poly-3-hydroxybutyrate-co-3-hydroxyvalerate (PHBV) copolymers with 3HV unit content ranging from 12 mol% to 72 mol% were evaluated. Samples were produced using a naturally enriched mixed culture fed with acetic and propionic acids. A range of feeding strategies was used to explore the manipulation of comonomer composition and sequence distribution of the monomeric units in order to influence mechanical properties. GC/MS, C-13 NMR and DSC analysis of the resulting solvent cast films revealed that the as-produced PHAs were a mixture of copolymers distinct in microstructure and/or composition. Atomic force microscopy demonstrated the formation of varying phase structures as well as surface morphologies. In spite of the range of microstructure or compositional variation that was achieved through feeding strategies, all samples but one exhibited mechanical properties similar to the homopolymer P(3HB). The one distinct copolymer, with 43 mol% 3HV content, showed significantly increased elongation to break, as assessed after 2 weeks of ageing. These results were attributed to the formation of different phase structures arising from the competition between cocrystallisation and phase segregation in blends of semicrystalline copolymers. (C) 2012 Elsevier Ltd. All rights reserved